Thermodynamics of the hydration equilibrium derived from the luminescence spectra of the solid state for the case of the Eu–EDTA system
Literature Information
R. Janicki, A. Mondry
The luminescence properties of two compounds, [C(NH2)3][Eu(EDTA)(H2O)3] (I) and [C(NH2)3]2[Yb0.97Eu0.03(EDTA)(H2O)2]ClO4·6H2O (II), were determined. The weighted sum of luminescence spectra of I and II was used to reproduce the spectra of the Eu–EDTA system in aqueous solution in the temperature range 276–363 K. By implementing this method it was possible to determine the thermodynamic functions (ΔH = 18113 ± 506 J mole−1 and ΔS = 62.5 ± 4.9 J mole−1 K−1) of the reaction [Eu(EDTA)(H2O)3]− ⇆ [Eu(EDTA)(H2O)2]− + H2O, which is difficult using other methods.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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