Phonon-assisted energy back transfer-induced multicolor upconversion emission of Gd2O3:Yb3+/Er3+ nanoparticles under near-infrared excitation
Literature Information
Jun Liu, Huawei Deng, Zhanyun Huang, Yueli Zhang, Dihu Chen, Yuanzhi Shao
Manipulation of upconversion (UC) emission is of particular importance for multiplexed bioimaging. Here, we precisely manipulate the UC color output by utilizing the phonon-assisted energy back transfer (EBT) process in ultra-small (sub-10 nm) Gd2O3:Yb3+/Er3+ UC nanoparticles (UCNPs). We synthesized the Gd2O3:Yb3+/Er3+ UCNPs by adopting the laser ablation in liquid (LAL) technique. The synthesized Gd2O3:Yb3+/Er3+ UCNPs are small spherical and monoclinic structures. Continuous color-tunable (from green to red) UC fluorescence emission is achieved by increasing the concentration of Yb3+ ions from 0 to 15 mol%. A phonon-assisted energy back transfer (EBT) process from Er3+ (4S3/2 → 4I13/2) to nearby Yb3+ (2F7/2 → 2F5/2), which can significantly enhance red emission at 672 nm and decrease green emission, is responsible for the color-tunable UC emission by increasing the Yb3+ concentration in Gd2O3:Yb3+/Er3+ UC nanoparticles.
Related Literature
Selective DMSO-induced conformational changes in proteins from Raman optical activity
Vanderlan S. Bolzani, Maysa Furlan, Ewan W. Blanch
DOI: 10.1039/C3CP53525H
On the signal depletion induced by stretching excitation of methane in the reaction with the F atom
Yuan Cheng, Huilin Pan
DOI: 10.1039/C3CP53036A
Marked enhancement in electron–hole separation achieved in the low bias region using electrochemically prepared Mo-doped BiVO4 photoanodes
Yiseul Park, Donghyeon Kang, Kyoung-Shin Choi
DOI: 10.1039/C3CP53649A
Mechanical and electronic properties of pristine and Ni-doped Si, Ge, and Sn sheets
Abhishek K. Singh
DOI: 10.1039/C3CP54655A
Eutectic melting in metal borohydrides
Mark Paskevicius, Drew A. Sheppard, Torben R. Jensen, Craig E. Buckley
DOI: 10.1039/C3CP53920B
Gas phase electronic spectra of carbon chains Cn (n = 6–9)
Xiaojing Chen, Mathias Steglich, Varun Gupta, Corey A. Rice, John P. Maier
DOI: 10.1039/C3CP54299H
Formation of supported rhodium clusters from mononuclear rhodium complexes controlled by the support and ligands on rhodium
Dicle Yardimci, Joseph D. Kistler, Bruce C. Gates
DOI: 10.1039/C3CP53057D
Kinetics of CH2OO reactions with SO2, NO2, NO, H2O and CH3CHO as a function of pressure
Daniel Stone, Laura Daubney, Neil U. M. Howes
DOI: 10.1039/C3CP54391A
Photodetachment and photodissociation of the linear OCuO− molecular anion: energy and time dependence of Cu− production
Richard Mabbs, Nicholas Holtgrewe, Diep Bich Dao, Joshua Lasinski
DOI: 10.1039/C3CP52986J
Imaging of spatial many-body wave functions via linear momentum measurements
Peer C. Fechner, Hanspeter Helm
DOI: 10.1039/C3CP53300J
You might also like
How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?
2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...
Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?
(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...
What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?
(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...
What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?
2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...
What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?
When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...
What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?
When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...
What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?
4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...
What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?
3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...
What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?
(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...
What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?
Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![1H-Imidazo[4,5-c]pyridine-7-carboxylic acid structure 1H-Imidazo[4,5-c]pyridine-7-carboxylic acid structure](https://static.chemtradehub.com/structs/123/1234616-39-7-1344.webp)
![1-Benzyl-1,7-diazaspiro[4.4]nonane dihydrochloride structure 1-Benzyl-1,7-diazaspiro[4.4]nonane dihydrochloride structure](https://static.chemtradehub.com/structs/115/1159822-71-5-0320.webp)