Internal dynamics in the molecular complex of CF3CN and H2O
Literature Information
Wei Lin, Anan Wu, Xin Lu, Xiao Tang, Daniel A. Obenchain, Stewart E. Novick
The rotational spectrum of trifluoroacetonitrile–water complex has been studied by pulsed-nozzle, Fourier transform microwave spectroscopy. Both a-type and b-type transitions have been observed. The rotational constants, centrifugal distortion constants, and the 14N nuclear quadrupole coupling constants have been determined. The complex is T-shaped, with the oxygen atom from the water located 3.135 Å from the carbon atom of CF3 of the trifluoroacetonitrile molecule.
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