Charge transfer, bonding conditioning and solvation effect in the activation of the oxygen reduction reaction on unclustered graphitic-nitrogen-doped graphene

Literature Information

Publication Date 2015-05-26
DOI 10.1039/C5CP00918A
Impact Factor 3.676
Authors

Enrique Herrero


View Original

Abstract

The monodentate associative chemisorption of molecular oxygen on unclustered graphitic-nitrogen-doped graphene requires two nitrogen dopants per activated molecule. Significant charge transfers from regions corresponding to distant nitrogen-dopants, the presence of a nitrogen-dopant adjacent to the carbon atom acting as an active site, which favours its transition from a sp2 hybridization state to sp3, and the solvation effect turn the investigated mechanism to a favourable process.

Related Literature

Telechelic polyethylene, poly(ethylene-co-vinyl acetate) and triblock copolymers based on ethylene and vinyl acetate by iodine transfer polymerization

Florian Baffie, Muriel Lansalot, Vincent Monteil, Franck D'Agosto

2022-03-15 Paper

DOI: 10.1039/D2PY00156J

Effect of anions on the phase transition temperature of two structurally isomeric polymers: poly(N-isopropylacrylamide) and poly(2-isopropyl-2-oxazoline)

Taehun Chung, Jihoon Han, Young Jae Kim, Kyeong-Jun Jeong, Jun Mo Koo, Jemin Lee, Hyung Gyu Park, Taiha Joo

2022-07-06 Paper

DOI: 10.1039/D2PY00543C

Contents list

2022-08-16 Front/Back Matter

DOI: 10.1039/D2PY90107B

The UCST phase transition of a dextran based copolymer in aqueous media with tunable thermoresponsive behavior

Shaon Dey, Arpita Roy, Kalipada Manna, Sagar Pal

2022-06-15 Communication

DOI: 10.1039/D2PY00626J

Ruthenium-catalyzed diazoacetate/cyclooctene metathesis copolymerization

Minghang Ji, Shengquan Zheng, Chen Zou, Min Chen

2022-07-30 Paper

DOI: 10.1039/D2PY00886F

High-efficiency solution-processed green thermally activated delayed fluorescence OLEDs using a polymer-small molecule mixed host

Seunguk Cho, Na Yeon Kwon, Chai Won Kim, Hyoseong Lee, Jung Min Ha, Hyung Jong Kim, Han Young Woo, Sungnam Park, Min Ju Cho, Dong Hoon Choi

2022-02-25 Paper

DOI: 10.1039/D1PY01700D

A dual initiator approach for oxygen tolerant RAFT polymerization

Nicholas G. Taylor, Marcus H. Reis, Travis P. Varner, Johann L. Rapp, Alexis Sarabia, Frank A. Leibfarth

2022-08-08 Paper

DOI: 10.1039/D2PY00603K

You might also like

155412-88-71-(3-Aminophenyl)-3-...
Compound Q&A

How should waste containing 1-(D-Ribofuranosyl)-1,4-dihydro-3-pyridinecarboxamide (CAS: 19132-12-8) be handled?

Waste containing 1-(D-Ribofuranosyl)-1,4-dihydro-3-pyridinecarboxamide (CAS: 191...

19132-12-81-(D-Ribofuranosyl)-...
Compound Q&A

What regulatory guidelines apply to 2-Methyl-2-propanyl 3-bromo-3-(hydroxymethyl)-1-azetidinecarboxylate (CAS: 2007919-81-3)?

2-Methyl-2-propanyl 3-bromo-3-(hydroxymethyl)-1-azetidinecarboxylate (CAS: 20079...

2007919-81-32-Methyl-2-propanyl ...
Compound Q&A

What is N-(4-Chloro-2-pyridinyl)acetamide (CAS: 245056-66-0)?

N-(4-Chloro-2-pyridinyl)acetamide (CAS: 245056-66-0) is a chemical compound with...

245056-66-0N-(4-Chloro-2-pyridi...
Compound Q&A

What is 5-Chloro-2-hydroxybenzoic acid (CAS: 321-14-2)?

5-Chloro-2-hydroxybenzoic acid, also known as 5-chlorosalicylic acid, is an arom...

321-14-25-Chloro-2-hydroxybe...
Compound Q&A

What precautions should be taken when handling 1,1-Dichloro-1-fluoroethane (CAS: 1717-00-6)?

When handling 1,1-Dichloro-1-fluoroethane (CAS: 1717-00-6), it is important to u...

1717-00-61,1-Dichloro-1-fluor...
Compound Q&A

What are the physical and chemical properties of Fmoc-(2S,3R)-3-phenylpyrrolidine-2-carboxylic acid (CAS: 281655-32-1)?

Fmoc-(2S,3R)-3-phenylpyrrolidine-2-carboxylic acid is a white crystalline solid ...

281655-32-1Fmoc-(2S,3R)-3-pheny...
Compound Q&A

What are the main uses of 4-Amino-5-bromo-2-pyridinecarboxylic acid (CAS: 1363381-01-4)?

4-Amino-5-bromo-2-pyridinecarboxylic acid is primarily used as a precursor in th...

1363381-01-44-Amino-5-bromo-2-py...
1007881-98-2(S)-tert-butyl 2-((2...
Compound Q&A

What precautions should be taken when handling 8-bromo-2,2-dimethyl-3,4-dihydro-2H-1,4-benzoxazin-3-one (CAS: 688363-73-7)?

When handling 8-bromo-2,2-dimethyl-3,4-dihydro-2H-1,4-benzoxazin-3-one, use prop...

688363-73-78-bromo-2,2-dimethyl...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.