Synergistic behaviour of ZnO nanoparticles and gemini surfactants on the dynamic and equilibrium oil/water interfacial tension
Literature Information
Tahereh Fereidooni Moghadam, Saeid Azizian, Shawn Wettig
In this work the effect of ZnO nanoparticles on the interfacial behaviour of gemini surfactants (12-3-12 and 14-3-14) at the oil/water interface was investigated. Equilibrium and dynamic interfacial tension in the absence and presence of ZnO was measured and compared. The results show that the synergistic interactions between the surfactants and nanoparticles decrease the interfacial tension beyond that observed for each component, alone. Modelling of dynamic data with two different models indicates that the mechanism of surfactant migration (with and without ZnO) is mixed diffusion-kinetic-control. The Gibbs free energy of micellization and the Gibbs free energy of adsorption in the absence and presence of ZnO were calculated and compared. Finally the effect of addition of ZnO nanoparticles on emulsion stability was also examined.
Recommended Journals
Related Literature
A laser trapping-spectroscopy study on the photocyanation of perylene across a single micrometre-sized oil droplets/water interface: droplet-size effects on photoreaction quantum yield
Fumihiko Kitagawa, Noboru Kitamura
DOI: 10.1039/B203259G
Reaction and dissociation mechanism control: the H2 + H2 system
Ernesto Garcia, Antonio Laganà
DOI: 10.1039/B205377B
Shock wave study of the unimolecular dissociation of H2O2 in its falloff range and of its secondary reactions
Ch. Kappel, K. Luther, J. Troe
DOI: 10.1039/B204364E
Computational studies of gas–carbon nanotube collision dynamics
Kim Bolton, Arne Rosén
DOI: 10.1039/B200581F
Chiral aggregates of indan-1-ol with secondary alcohols and water: Laser spectroscopy in supersonic beams
A. Paladini, M. Satta, D. Catone, S. Piccirillo, M. Speranza
DOI: 10.1039/B204909K
FTIR study of low-temperature CO adsorption on high surface area tin(iv) oxide: Probing Lewis and Brønsted acidity
Patrick Gélin, Laurent Périer-Camby, Hélène Praliaud, Gérard Thomas
DOI: 10.1039/B206336K
A quasiclassical trajectory and quantum mechanical study of the O(1D) + D2 reaction dynamics. Comparison with high resolution molecular beam experiments
V. J. Herrero, B. Martínez-Haya
DOI: 10.1039/B203755F
Vibrational predissociation of ArHF: a test of global semiempirical potential energy surfaces
Roman V. Krems, Sture Nordholm
DOI: 10.1039/B204480N
Optically induced birefringence in a series of analogous diols
DOI: 10.1039/B203010A
A physical mechanism for large-ion selectivity of ion channels
Douglas Henderson, Robert S. Eisenberg
DOI: 10.1039/B203184A
You might also like
How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?
Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...
What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?
Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...
Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?
Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...
Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?
Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...
Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?
Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...
Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?
(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...
How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?
(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...
What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?
Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...
What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?
6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...
Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?
3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![4-(4-{4-[4-Fluoro-3-(trifluoromethyl)phenyl]-1-methyl-1H-imidazol-2-yl}-1-piperidinyl)-1H-pyrazolo[3,4-d]pyrimidine 4-methylbenzenesulfonate (1:1) structure 4-(4-{4-[4-Fluoro-3-(trifluoromethyl)phenyl]-1-methyl-1H-imidazol-2-yl}-1-piperidinyl)-1H-pyrazolo[3,4-d]pyrimidine 4-methylbenzenesulfonate (1:1) structure](https://static.chemtradehub.com/structs/108/1082949-68-5-00b6.webp)
