Optically induced birefringence in a series of analogous diols

Literature Information

Publication Date 2002-08-05
DOI 10.1039/B203010A
Impact Factor 3.676
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Abstract

Optically induced birefringence has been analysed in a series of analogous diols containing heteroatoms, such as O, N or S. The presence of a heteroatom in a diol molecule can change the arrangement of hydrogen bonding and, consequently, the arrangement of molecules. This hypothesis was confirmed by the results of our study. The measurements were performed at temperatures from 280 to 350 K. The values of the absolute and molar Kerr constants were calculated. The character and magnitude of the temperature changes of molar Kerr constant depend on the type of the heteroatom. According to the theory of the optical Kerr effect such a temperature behaviour indicates the presence of molecular interactions leading to formation of molecular aggregates. The sign of the calculated values of angular correlation factor indicates the predominant parallel arrangement of molecules in such molecular ensembles.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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