CO-enabled rhenium hydride catalyst for directed C(sp2)–H bond alkylation with olefins‡
Literature Information
Publication Date
2015-02-03
DOI
10.1039/C4QO00329B
Impact Factor
5.281
Authors
Hongming Jin, Zhengbo Zhu, Ning Jin, Jin Xie, Yixiang Cheng
View Original
Abstract
We report the first example of CO-enabled rhenium hydride complex-catalyzed inter- and intra-molecular hydroarylation of activated alkenes, with a broad reaction scope. α,β-Unsaturated ketones, esters and amides are all suitable for this transformation. It affords a novel and convenient protocol to construct 3-methylindolones. In addition, mechanistic investigations suggest that a rhenium carbonyl hydride species may act as a key intermediate.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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CAS Number:
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Molecular Formula:
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