![5-Chloropyrrolo[2,1-f][1,2,4]triazin-4(3H)-one structure](https://static.chemtradehub.com/structs/888/888720-60-3-4f7c.webp "5-Chloropyrrolo[2,1-f][1,2,4]triazin-4(3H)-one structure")
Thiol-reactive Passerini-methacrylates and polymorphic surface functional soft matter nanoparticles via ethanolic RAFT dispersion polymerization and post-synthesis modification
Literature Information
Publication Date
2015-01-02
DOI
10.1039/C4PY01558D
Impact Factor
5.582
Authors
Yiwen Pei, Janina-Miriam Noy, Peter J. Roth, Andrew B. Lowe
View Original
Abstract
RAFT dispersion polymerization (RAFTDP) is used to prepare reactive nanoparticles via the incorporation of Passerini-derived methacrylic comonomers containing pentafluorophenyl (PFP) groups. Copolymerization of 2-(dimethylamino)ethyl methacrylate with a Passerini comonomer gives copolymers suitable as macro-CTAs for ethanolic RAFTDP of 3-phenylpropyl methacrylate. Reaction of the PFP residues with functional thiols offers an approach for preparing surface modified nanoparticles.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
4-(4-Methoxyphenyl)-5-methyl-1,3-thiazol-2-amine
CAS Number:
105512-88-7
Molecular Formula:
C11H12N2OS
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