Interfacial charge transfer enhancement via formation of binary molecular assemblies on electronically corrugated boron nitride

Literature Information

Publication Date 2019-11-15
DOI 10.1039/C9CP04853G
Impact Factor 3.676
Authors

A. Tan, P. P. Zhang


View Original

Abstract

Using scanning tunneling microscopy/spectroscopy (STM/STS) in conjunction with finite element simulation, we investigate the interfacial behaviors in single-component zinc phthalocyanine (ZnPc) and hexadecafluorinated zinc phthalocyanine (F16ZnPc) molecular overlayers as well as their 1 : 1 mixed-phase superstructures on h-BN/Cu(111). We show that the formation of the binary molecular superstructure drastically increases the charge transfer between F16ZnPc molecules and the substrate, which is attributed to the greater electrostatic stability of the binary assembly compared to that of the pure phase. This study highlights the significant complication in the design of donor–acceptor molecular thin films as the presence of the substrate, even a weakly interacting one, such as h-BN/metal, can still perturb the intermolecular charge transfer and thereby the physical behaviors of the hybrid system via interfacial processes.

Related Literature

Eco-friendly one-shot approach for producing a functionalized nano-torrefied biomass: a new application of ball milling technology

Aida Kiani, Elena Lamberti, Gianluca Viscusi, Paola Giudicianni, Corinna Maria Grottola, Raffaele Ragucci, Giuliana Gorrasi, Maria Rosaria Acocella

2023-12-04 Paper

DOI: 10.1039/D3MA00804E

Role of thermal and reactive oxygen species-responsive synthetic hydrogels in localized cancer treatment (bibliometric analysis and review)

Yohannis Wondwosen Ahmed, Tsung-Yun Wu, Haile Fentahun Darge

2023-11-17 Review Article

DOI: 10.1039/D3MA00341H

Inside front cover

2023-11-27 Cover

DOI: 10.1039/D3MA90099A

Castor oil-derived polyurethane networks multiple recyclability based on reversible dynamic acetal bond

Xiaolin Wang, Md Ahsan Habib, Jin Zhu, Jing Chen

2023-11-07 Paper

DOI: 10.1039/D3MA00464C

The synthesis and combined electrical–magnetic and toxic dye sequestration properties of a Cr(iii)-metallogel

Krishna Sundar Das, Mainak Das, Sayan Saha, Amit Adhikary, Sukhen Bala, Partha Pratim Ray, Raju Mondal

2023-11-03 Paper

DOI: 10.1039/D3MA00645J

A comprehensive insight into deep-level defect engineering in antimony chalcogenide solar cells

Swapnil Barthwal, Siddhant Singh, Abhishek K. Chauhan, Nimitha S. Prabhu, Akila G. Prabhudessai, K. Ramesh

2023-10-13 Review Article

DOI: 10.1039/D3MA00479A

Inside front cover

2023-12-11 Cover

DOI: 10.1039/D3MA90103C

You might also like

Compound Q&A

What are the main uses of (5-Sulfamoyl-3-pyridinyl)boronic acid (CAS: 951233-61-7)?

(5-Sulfamoyl-3-pyridinyl)boronic acid is primarily used in chemical synthesis, p...

951233-61-7(5-Sulfamoyl-3-pyrid...
Compound Q&A

How is Benzyl 2-methyl-2-(methylsulfonyl)-4-pentenoate (CAS: 1942858-50-5) typically synthesized?

Benzyl 2-methyl-2-(methylsulfonyl)-4-pentenoate is typically synthesized via est...

1942858-50-5Benzyl 2-methyl-2-(m...
Compound Q&A

What precautions should be taken when handling 8-Fluoroquinolin-6-ol (CAS: 209353-22-0)?

When handling 8-Fluoroquinolin-6-ol (CAS: 209353-22-0), it is important to use p...

209353-22-08-Fluoroquinolin-6-o...
Compound Q&A

What are the physical and chemical properties of 1,3-Dibromo-5-(2-methyl-2-propanyl)benzene (CAS: 129316-09-2)?

1,3-Dibromo-5-(2-methyl-2-propanyl)benzene (CAS: 129316-09-2) is a crystalline c...

129316-09-21,3-Dibromo-5-(2-met...
Compound Q&A

What industries use Ethyl 7-chloro-4-oxo-1-(1,3-thiazol-2-yl)-1,4-dihydro-1,8-naphthyridine-3-carboxylate (CAS: 174726-87-5)?

Ethyl 7-chloro-4-oxo-1-(1,3-thiazol-2-yl)-1,4-dihydro-1,8-naphthyridine-3-carbox...

174726-87-5Ethyl 7-chloro-4-oxo...
Compound Q&A

What precautions should be taken when handling Delta-7-Avenasterol (CAS: 23290-26-8)?

When handling Delta-7-Avenasterol (CAS: 23290-26-8), it is important to wear app...

23290-26-8Delta-7-Avenasterol
872992-20-6N-({(5R)-3-[3-Fluoro...
Compound Q&A

What precautions should be taken when handling 2-Methyl-2-proanyl 4-[(2-aminophenyl)amino]-1-piperidinecarboxylate (CAS: 79099-00-6)?

When handling 2-Methyl-2-proanyl 4-[(2-aminophenyl)amino]-1-piperidinecarboxylat...

79099-00-62-Methyl-2-propanyl ...
Compound Q&A

What is N-Methyl-4-chlorobenzylamine hydrochloride (CAS: 65542-24-7)?

N-Methyl-4-chlorobenzylamine hydrochloride (CAS: 65542-24-7) is a organic compou...

65542-24-7N-Methyl-4-chloroben...
Compound Q&A

Is [2-(Dodecyloxy)ethoxy]acetic acid (CAS: 27306-90-7) safe?

[2-(Dodecyloxy)ethoxy]acetic acid (CAS: 27306-90-7) is generally considered safe...

27306-90-7[2-(Dodecyloxy)ethox...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.