![2-Methyl-2-propanyl [(2S)-1-hydroxy-3-(4-hydroxyphenyl)-2-propanyl]carbamate structure](https://static.chemtradehub.com/structs/833/83345-46-4-eec2.webp "2-Methyl-2-propanyl [(2S)-1-hydroxy-3-(4-hydroxyphenyl)-2-propanyl]carbamate structure")
2-Methyl-2-propanyl [(2S)-1-hydroxy-3-(4-hydroxyphenyl)-2-propanyl]carbamate
CAS Number:
83345-46-4
Molecular Formula:
C14H21NO4
Well-defined polyethylene molecular brushes by polyhomologation and ring opening metathesis polymerization
Literature Information
Publication Date
2014-07-28
DOI
10.1039/C4PY00815D
Impact Factor
5.582
Authors
Yves Gnanou
View Original
Abstract
A novel strategy using polyhomologation and ring opening metathesis polymerization (ROMP) has been developed for the synthesis of well-defined polyethylene (PE) molecular brushes. Polyhomologation was used to afford an OH-terminated PE, which after transformation to the norbornyl PE macromonomer was subjected to ROMP. Kinetics of ROMP of the PE macromonomer was studied by in situ1H NMR monitoring. The brush structure was proved from HT-GPC, 1H NMR and DSC results.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![(2E)-4-[(1R,2S,8R,19S,21R)-14-Hydroxy-11-isopropenyl-8,23,23-trimethyl-5-(3-methyl-2-buten-1-yl)-16,20-dioxo-3,7,22-trioxaheptacyclo[17.4.1.1~8,12~.0~2,17~.0~2,21~.0~4,15~.0~6,13~]pentacosa-4(15),5,13
,17-tetraen-21-yl]-2-methyl-2-butenoic acid structure](https://static.chemtradehub.com/structs/173/173867-04-4-d2d3.webp "(2E)-4-[(1R,2S,8R,19S,21R)-14-Hydroxy-11-isopropenyl-8,23,23-trimethyl-5-(3-methyl-2-buten-1-yl)-16,20-dioxo-3,7,22-trioxaheptacyclo[17.4.1.1~8,12~.0~2,17~.0~2,21~.0~4,15~.0~6,13~]pentacosa-4(15),5,13
,17-tetraen-21-yl]-2-methyl-2-butenoic acid structure")
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