![4-[(2,4-Dihydroxyphenyl)diazenyl]-5-hydroxy-2,7-naphthalenedisulfonic acid structure](https://static.chemtradehub.com/structs/362/3627-01-8-79ac.webp "4-[(2,4-Dihydroxyphenyl)diazenyl]-5-hydroxy-2,7-naphthalenedisulfonic acid structure")
4-[(2,4-Dihydroxyphenyl)diazenyl]-5-hydroxy-2,7-naphthalenedisulfonic acid
CAS Number:
3627-01-8
Molecular Formula:
C16H12N2O9S2
Polythiophenes with vinylene linked ortho, meta and para-carborane sidechains
Literature Information
Publication Date
2014-07-17
DOI
10.1039/C4PY00767K
Impact Factor
5.582
Authors
Jonathan Marshall, Jake Hooton, Yang Han, Adam Creamer, Raja Shahid Ashraf, Yoann Porte, Thomas D. Anthopoulos, Paul N. Stavrinou, Martyn A. McLachlan, Hugo Bronstein, Peter Beavis, Martin Heeney
View Original
Abstract
We report the synthesis of a series of novel polythiophenes with vinylene linked pendant carborane sidechains. Polymers containing ortho, meta and para substituted carborane linked via a cis or trans double bond are reported. The inclusion of carborane sidechains is demonstrated to afford soluble polymers without the presence of any additional alkyl groups. The choice of carborane and double bond isomer is shown to influence the optoelectronic, photovoltaic and charge-transporting properties of the polymer. In particular the incorporation of ortho-carborane was shown to have a pronounced electron withdrawing effect resulting in a substantial increase in polymer ionisation potential. Field effect transistors and solar cells devices fabricated from the various isomers showed significant differences in performance.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
Benzyl 3-(aminomethyl)piperidine-1-carboxylate hydrochloride
CAS Number:
1186663-23-9
Molecular Formula:
C14H21ClN2O2
![[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/871/871332-68-2-0e3b.webp "[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure")
[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid
CAS Number:
871332-68-2
Molecular Formula:
C11H15BClNO3
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