Gas-phase spectroscopy of singly reduced tris(bipyridine)ruthenium ions, Ru(bipy)3+

Literature Information

Publication Date 2015-01-13
DOI 10.1039/C4CP05477F
Impact Factor 3.676
Authors

Camilla Skinnerup Byskov, J. Mathias Weber, Steen Brøndsted Nielsen


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Abstract

Light absorption in the visible region by isolated Ru(bipy)3+ (bipy = 2,2′-bipyridine) monocations, prepared in vacuo by reduction of dications in collisional electron transfer from cesium atoms, was recorded using photodissociation mass spectroscopy and found to be broad and similar to that of acetonitrile-solvated ions (maximum at 520 nm).

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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