Enhanced electrochromic properties of a polypyrrole–indigo carmine–gold nanoparticles nanocomposite

Literature Information

Publication Date 2014-11-17
DOI 10.1039/C4CP04262J
Impact Factor 3.676
Authors

L. F. Loguercio, C. C. Alves, A. Thesing, J. Ferreira


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Abstract

An indigo carmine doped polypyrrole embedded with gold nanoparticles nanocomposite (PPy–IC–Aunanop) was synthesized by in situ electrochemical polymerization of polypyrrole in the presence of HAuCl4. The nanocomposite was characterized by in situ spectroelectrochemical experiments to study the effect of embedded gold nanoparticles on the electrochromic properties of the material. The results show the formation of a nanocomposite presenting enhanced electrochromic and optical properties, higher electroactivity and 10% lower band-gap energies. The PPy–IC–Aunanop presented a two-fold increase in optical contrast when compared to PPy–IC, in addition to better optical stability.

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Contents list

Front/Back Matter

DOI: 10.1039/C8CP90067A

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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