Electronic effects of ligand substitution on metal–organic framework photocatalysts: the case study of UiO-66
Literature Information
Lijuan Shen, Ruowen Liang, Mingbu Luo, Fenfen Jing, Ling Wu
UiO-66-X (X = H, NH2, NO2, Br) have been successfully synthesized and tested for their photocatalytic activity in water treatment. Results show that electronic effect of the ligand substituents greatly affects the photocatalytic activity of UiO-66. The rates obtained by different substituents are linearly correlated with their Hammett coefficients.
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