A linear diffusion model for ion current across blocking grain boundaries in oxygen-ion and proton conductors

Literature Information

Publication Date 2014-06-06
DOI 10.1039/C4CP01254B
Impact Factor 3.676
Authors

Seong K. Kim, Sergey Khodorov, Igor Lubomirsky, Sangtae Kim


View Original

Abstract

We demonstrate the applicability of the linear diffusion model recently proposed for the current–voltage, Igb–Ugb, characteristics of blocking grain boundaries in solid electrolytes to various oxygen-ion and proton conductors: the model precisely reproduces the Igb–Ugb characteristics of La-, Sm-, Gd-, and Y-doped ceria as well as Y-doped barium zirconate to provide accurate explanations to the “power law” behavior of the Igb–Ugb relationship, i.e. Igb ∝ Ugbn, experimentally observed. The model also predicts that the grain-boundary potential, Ψgb, in doped ceria weakly depends on temperature, if the trapped charge remains constant, and that the value of Ψgb can be determined from the value of the power n. Furthermore, the model provides a plausible explanation for the increase in the Ψgb with temperature observed for the proton conductor in which the concentration of the charge carrier decreases with temperature. Hence, it is evident that the linear diffusion model is robust and applicable to grain boundaries in a large variety of practically important solid electrolytes.

Related Literature

Inside front cover

Cover

DOI: 10.1039/C8CP91900C

Inside front cover

Cover

DOI: 10.1039/C8CP90071J

Visible light-triggered fluorescence and pH modulation using metastable-state photoacids and BODIPY

Parth K. Patel, Juan E. Arias, Renan S. Gongora, Aurélien Moncomble, Stéphane Aloïse, Karin Y. Chumbimuni-Torres

2018-08-08 Communication

DOI: 10.1039/C8CP03977A

Time dependence of NMR observables reveals salient differences in the accumulation of early aggregated species between human islet amyloid polypeptide and amyloid-β

Anaïs R. F. Hoffmann, Lucie Caillon, Lilian Shadai Salazar Vazquez, Pierre-Alexandre Spath, Ludovic Carlier, Lucie Khemtémourian, Olivier Lequin

2018-03-20 Paper

DOI: 10.1039/C7CP07516B

Computational strategies to probe CH activation in dioxo-dicopper complexes

Zhenzhuo Lan, Shaama Mallikarjun Sharada

2018-09-27 Paper

DOI: 10.1039/C8CP05096A

Synthesis of corrugated C-based nanostructures by Br-corannulene oligomerization

Marco Smerieri, Lara Ferrighi, Silvia Nappini, Luca Vaghi, Antonio Papagni, Cristiana Di Valentin, Federica Bondino, Letizia Savio

2018-09-25 Paper

DOI: 10.1039/C8CP04791J

A high pressure Raman study on confined individual iodine molecules as molecular probes of structural collapse in the AlPO4-5 framework

Shuanglong Chen, Zhen Yao, Hang Lv, Enlai Dong, Xibao Yang, Ran Liu, Bingbing Liu

2018-09-29 Paper

DOI: 10.1039/C8CP04415E

Theoretical study of radiative and nonradiative decay rates for Cu(i) complexes with double heteroleptic ligands

Yuannan Chen, Aimin Ren, Zhongyue Yang, Tengfei He, Xiaoli Ding, Hongxing Zhang, Luyi Zou

2018-03-07 Paper

DOI: 10.1039/C8CP00525G

You might also like

155412-88-71-(3-Aminophenyl)-3-...
Compound Q&A

How should waste containing 1-(D-Ribofuranosyl)-1,4-dihydro-3-pyridinecarboxamide (CAS: 19132-12-8) be handled?

Waste containing 1-(D-Ribofuranosyl)-1,4-dihydro-3-pyridinecarboxamide (CAS: 191...

19132-12-81-(D-Ribofuranosyl)-...
Compound Q&A

What regulatory guidelines apply to 2-Methyl-2-propanyl 3-bromo-3-(hydroxymethyl)-1-azetidinecarboxylate (CAS: 2007919-81-3)?

2-Methyl-2-propanyl 3-bromo-3-(hydroxymethyl)-1-azetidinecarboxylate (CAS: 20079...

2007919-81-32-Methyl-2-propanyl ...
Compound Q&A

What is N-(4-Chloro-2-pyridinyl)acetamide (CAS: 245056-66-0)?

N-(4-Chloro-2-pyridinyl)acetamide (CAS: 245056-66-0) is a chemical compound with...

245056-66-0N-(4-Chloro-2-pyridi...
Compound Q&A

What is 5-Chloro-2-hydroxybenzoic acid (CAS: 321-14-2)?

5-Chloro-2-hydroxybenzoic acid, also known as 5-chlorosalicylic acid, is an arom...

321-14-25-Chloro-2-hydroxybe...
Compound Q&A

What precautions should be taken when handling 1,1-Dichloro-1-fluoroethane (CAS: 1717-00-6)?

When handling 1,1-Dichloro-1-fluoroethane (CAS: 1717-00-6), it is important to u...

1717-00-61,1-Dichloro-1-fluor...
Compound Q&A

What are the physical and chemical properties of Fmoc-(2S,3R)-3-phenylpyrrolidine-2-carboxylic acid (CAS: 281655-32-1)?

Fmoc-(2S,3R)-3-phenylpyrrolidine-2-carboxylic acid is a white crystalline solid ...

281655-32-1Fmoc-(2S,3R)-3-pheny...
Compound Q&A

What are the main uses of 4-Amino-5-bromo-2-pyridinecarboxylic acid (CAS: 1363381-01-4)?

4-Amino-5-bromo-2-pyridinecarboxylic acid is primarily used as a precursor in th...

1363381-01-44-Amino-5-bromo-2-py...
1007881-98-2(S)-tert-butyl 2-((2...
Compound Q&A

What precautions should be taken when handling 8-bromo-2,2-dimethyl-3,4-dihydro-2H-1,4-benzoxazin-3-one (CAS: 688363-73-7)?

When handling 8-bromo-2,2-dimethyl-3,4-dihydro-2H-1,4-benzoxazin-3-one, use prop...

688363-73-78-bromo-2,2-dimethyl...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.