Electrochemistry of orthosilicate-based lithium battery cathodes: a perspective

Literature Information

Publication Date 2014-04-15
DOI 10.1039/C4CP00511B
Impact Factor 3.676
Authors

Stefania Ferrari, Doretta Capsoni, Simone Casino, Matteo Destro, Claudio Gerbaldi, Marcella Bini


View Original

Abstract

Lithium metal orthosilicates are attracting a lot of attention owing to their promising prospects as potential high capacity cathode materials for Li-ion batteries. Currently, great efforts are being made in order to achieve the full theoretical specific capacity of 330 mA h g−1, but many issues remain unsolved (e.g., poor structural and cycling stability), which limit their practical application. The present perspective highlights the importance of assessing the electrochemical behaviour of Li2(Fe,Mn)SiO4 by combining an arsenal of characterization techniques both spectroscopic and structural, in and ex situ. Here, we review the most recent achievements in the investigation of the electrochemical performance of lithium metal orthosilicate cathodes and, through some of our recent results, we attempt to clarify the relationship between the structure and electrochemistry of these compounds.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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