The “excited state C–C bond cleavage–luminescence” phenomenon of a biphenyl-substituted methylenecyclopropane triggered by intermolecular energy transfer from triplet benzophenone‡

Literature Information

Publication Date 2014-09-16
DOI 10.1039/C4CC06847E
Impact Factor 6.222
Authors

Taiki Kido


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Abstract

Existence of the “excited state C–C bond cleavage–luminescence” phenomenon was demonstrated by utilizing intermolecular energy transfer from the excited-triplet benzophenone to 2,2-di(4-biphenylyl)-1-methylenecyclopropane (3). An excellent linear relationship between the intensity of the excitation laser light and that of luminescence clearly shows that formation of the corresponding excited trimethylenemethane biradical 34˙˙* proceeds via a one-photon route.

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