Solvent free selective dehydrogenation of indolic and carbazolic molecules with an iridium pincer catalyst
Literature Information
Daniel F. Brayton, Craig M. Jensen
A previously known iridium POCOP pincer catalyst was found to selectively dehydrogenate the heterocyclic portion of several indolic and carbazolic molecules. These molecules were found to have an “activity window” (172–178 °C) upon which only the heterocyclic ring underwent dehydrogenation. All reactions were run solvent free, yields for selected substrates were excellent, and the products were isolated by either distillation or alumina plug filtration.
Related Literature
Structure–selectivity relationships for polyol hydrogenolysis over Ru catalysts
Benjamin Kühne, Sarah Glasder, Herbert Vogel, Christine Kröner, Alireza Haji-Begli, Markwart Kunz, Sebastian Kunz
DOI: 10.1039/D0RE00170H
Revisiting the long-chain branch formation mechanism in metallocene catalyzed polyethylenes
Vahid Karimkhani, Faramarz Afshar-Taromi, Florian J. Stadler
DOI: 10.1039/C3PY00319A
End-functional stereoregular poly(methyl methacrylate) with clickable CC bonds: facile synthesis and thiol–ene reaction
Yasuhiro Kohsaka, Takashi Kurata, Tatsuki Kitayama
DOI: 10.1039/C3PY00799E
Effect of ionic content on ballistic self-healing in EMAA copolymers and ionomers
John R. Pflug, Russell J. Varley
DOI: 10.1039/C3PY00095H
Intracellular pH-activated PEG-b-PDPA wormlike micelles for hydrophobic drug delivery
Haijun Yu, Zhiai Xu, Dangge Wang, Xianzhi Chen, Zhiwen Zhang, Qi Yin, Yaping Li
DOI: 10.1039/C3PY00849E
Protected N-heterocyclic carbenes as latent pre-catalysts for the polymerization of ε-caprolactone
Stefan Naumann, Friedrich Georg Schmidt, Wolfgang Frey
DOI: 10.1039/C3PY00548H
Interfacing a phosphate catalytic reaction with a microbial metabolism for the production of azaphilone alkaloids
Lujie Liu, Jiawei Zheng, Xuehong Zhang, Zhilong Wang
DOI: 10.1039/D0RE00355G
Pretreatment and fermentation of lignocellulosic biomass: reaction mechanisms and process engineering
William Doherty, Luqman Atanda, Lalehvash Moghaddam
DOI: 10.1039/D0RE00241K
Synthesis of multi-responsive polymeric nanocarriers for controlled release of bioactive agents
Guohua Jiang, Caiyi Mai
DOI: 10.1039/C3PY00746D
You might also like
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry












![5,7-Dichloro-2-(methylsulfanyl)[1,3]thiazolo[4,5-d]pyrimidine structure 5,7-Dichloro-2-(methylsulfanyl)[1,3]thiazolo[4,5-d]pyrimidine structure](https://static.chemtradehub.com/structs/877/87789-35-3-e0b4.webp)
![1,4-Dioxaspiro[4.5]dec-7-en-8-ylboronic acid structure 1,4-Dioxaspiro[4.5]dec-7-en-8-ylboronic acid structure](https://static.chemtradehub.com/structs/850/850567-90-7-6fff.webp)
