End-functional stereoregular poly(methyl methacrylate) with clickable CC bonds: facile synthesis and thiol–ene reaction
Literature Information
Yasuhiro Kohsaka, Takashi Kurata, Tatsuki Kitayama
Stereoregular poly(methyl methacrylate) with a clickable CC ω-end by a Michael-addition type thiol–ene reaction was synthesized through an anion terminating reaction with α-(halomethyl)acrylates. The thiol–ene click reaction at the ω-end provided various ω-functional polymers quantitatively.
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