Facile synthesis of poly(3-hexylthiophene)-block-poly(ethylene oxide) copolymersvia Steglich esterification

Literature Information

Publication Date 2013-05-13
DOI 10.1039/C3PY00505D
Impact Factor 5.582
Authors

Harikrishna Erothu, Arun A. Sohdi, Anitha C. Kumar, Andrew J. Sutherland, Christine Dagron-Lartigau, Ahmed Allal, Roger C. Hiorns, Paul D. Topham


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Abstract

Poly(ethylene oxide) has been coupled to poly(3-hexylthiophene) using esterification to produce pure diblock copolymers, highly relevant for use in organic electronic devices. The new synthetic route described herein uses a metal-free coupling step, for the first time, to afford well-defined polymers in high yields following facile purification.

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