N-Acetoxy-phthalimide (NAPI) as a new H-abstracting agent at high temperature: application to the melt functionalization of polyethylene
Literature Information
Publication Date
2013-03-15
DOI
10.1039/C3PY00246B
Impact Factor
5.582
Authors
Denis Bélékian, Philippe Cassagnau, Jean-Jacques Flat, Sébastien Quinebeche, Laurent Autissier, Denis Bertin, Didier Siri, Didier Gigmes, Yohann Guillaneuf, Philippe Chaumont, Emmanuel Beyou
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Abstract
A new H-abstracting agent, N-acetoxy-phthalimide (NAPI), was designed that cleaves mainly homolytically into acyloxyl and aminyl radicals at 190 °C. Melt PE grafting experiments confirmed the H-abstraction efficiency of NAPI. It was also shown that the grafting of maleic anhydride increased and at the same time undesired crosslinking lowered compared to peroxides.
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Polymer Chemistry
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