Assembly of large simple 1D and rare polycatenated 3D molecular ladders from T-shaped building blocks containing a new, long N,N′-bidentate ligand

Literature Information

Publication Date 2004-08-20
DOI 10.1039/B406126H
Impact Factor 6.222
Authors

Cheng-Yong Su, Andrea M. Goforth, Mark D. Smith, Hans-Conrad zur Loye


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Abstract

Molecular ladders [Co2(nbpy4)3(NO3)4]·solvents and [Cd2(nbpy4)3(NO3)4] (nbpy4 = N,N′-bis-(4-pyridinylmethylene)-1,5-naphthalenediamine) were synthesized via self-assembly; the former is a large, simple, noninterpenetrated 1D ladder that contains guest solvent molecules between the rungs, while the latter exists as 1D ladders in a rare four-fold interlocked 3D structure.

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