Assembly of large simple 1D and rare polycatenated 3D molecular ladders from T-shaped building blocks containing a new, long N,N′-bidentate ligand
Literature Information
Cheng-Yong Su, Andrea M. Goforth, Mark D. Smith, Hans-Conrad zur Loye
Molecular ladders [Co2(nbpy4)3(NO3)4]·solvents and [Cd2(nbpy4)3(NO3)4] (nbpy4 = N,N′-bis-(4-pyridinylmethylene)-1,5-naphthalenediamine) were synthesized via self-assembly; the former is a large, simple, noninterpenetrated 1D ladder that contains guest solvent molecules between the rungs, while the latter exists as 1D ladders in a rare four-fold interlocked 3D structure.
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![1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure 1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure](https://static.chemtradehub.com/structs/97-/97-77-8-f3e4.webp)
