Dual functionality of formamidinepolymers, as ligands and as bases, in ruthenium-catalysed hydrogen evolution from formic acid

Literature Information

Publication Date 2013-03-06
DOI 10.1039/C3PY00120B
Impact Factor 5.582
Authors

Stephan Enthaler, Henrik Junge, Anna Fischer, Anja Kammer, Jan Dirk Epping


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Abstract

In the present study, the ruthenium-catalysed decomposition of formic acid to yield hydrogen has been examined. A ruthenium complex modified polyformamidine network was used as a solid catalyst. As a dual support the polyformamidine acts both as a ligand and as a base for the activation of formic acid.

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