Highly effective tandem hydroformylation–acetalization of olefins using a long-life Brønsted acid–Rh bifunctional catalyst in ionic liquid–alcohol systems

Literature Information

Publication Date 2013-08-28
DOI 10.1039/C3GC41231H
Impact Factor 10.182
Authors

Kun Zhao, Feifei Cui, Fangfang Kong, Qiangqiang Liu


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Abstract

A robust and highly effective tandem hydroformylation–acetalization of olefins using a Brønsted acid–Rh bifunctional catalyst (ARBC) in ionic liquid–alcohol systems is reported. The key feature of the ARBC is its use of a zwitterionic phosphine ligand bearing an amino acid tag. This novel ARBC shows an excellent catalytic efficiency and a long service life without a significant drop in both the hydroformylation efficiency and the acetalization efficiency or Rh loss for more than seventeen cycles. We believe that the long-term high activity and acetal selectivity mainly benefit from the synergy between the acidic active site and the Rh active site on the ARBC and the highly effective immobilization and recycling of ARBC in ionic liquid–alcohol systems due to the strong affinity of ARBC for the ionic liquid.

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Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.

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