Robust porphyrincatalysts immobilized on biogenous iron oxide for the repetitive conversions of epoxides and CO2 into cyclic carbonates
Literature Information
Tadashi Ema, Yuki Miyazaki, Tomoya Taniguchi, Jun Takada
Metalloporphyrins were immobilized on biogenous iron oxide (BIO) produced by iron-oxidizing bacteria, Leptothrix ochracea. These organic–inorganic hybrid materials were used as immobilized catalysts for the synthesis of cyclic carbonates from epoxides and CO2 under solvent-free conditions. ZnII porphyrin immobilized via four tetraalkylammonium bromide groups showed high catalytic activity and reusability at a catalyst loading of 0.1 mol%. The product was obtained in 99% yield after nine times reuse, and the substrate scope was broad.
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