Robust porphyrincatalysts immobilized on biogenous iron oxide for the repetitive conversions of epoxides and CO2 into cyclic carbonates

Literature Information

Publication Date 2013-07-18
DOI 10.1039/C3GC41055B
Impact Factor 10.182
Authors

Tadashi Ema, Yuki Miyazaki, Tomoya Taniguchi, Jun Takada


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Abstract

Metalloporphyrins were immobilized on biogenous iron oxide (BIO) produced by iron-oxidizing bacteria, Leptothrix ochracea. These organic–inorganic hybrid materials were used as immobilized catalysts for the synthesis of cyclic carbonates from epoxides and CO2 under solvent-free conditions. ZnII porphyrin immobilized via four tetraalkylammonium bromide groups showed high catalytic activity and reusability at a catalyst loading of 0.1 mol%. The product was obtained in 99% yield after nine times reuse, and the substrate scope was broad.

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