Structural dynamics effects on the ultrafast chemical bond cleavage of a photodissociation reaction
Literature Information
María E. Corrales, Garikoitz Balerdi, Rebeca de Nalda, Luis Bañares, Ahmed H. Zewail
The correlation between chemical structure and dynamics has been explored in a series of molecules with increasing structural complexity in order to investigate its influence on bond cleavage reaction times in a photodissociation event. Femtosecond time-resolved velocity map imaging spectroscopy reveals specificity of the ultrafast carbon–iodine (C–I) bond breakage for a series of linear (unbranched) and branched alkyl iodides, due to the interplay between the pure reaction coordinate and the rest of the degrees of freedom associated with the molecular structure details. Full-dimension time-resolved dynamics calculations support the experimental evidence and provide insight into the structure–dynamics relationship to understand structural control on time-resolved reactivity.
Related Literature
Fluorescence based strategies for genetic analysis
Rohan T. Ranasinghe, Tom Brown
DOI: 10.1039/B509522K
Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality
Luís C. Branco, Pedro M. P. Gois, Nuno M. T. Lourenço, Vanya B. Kurteva, Carlos A. M. Afonso
DOI: 10.1039/B600816J
Easy access to the family of thiazole N-oxides using HOF·CH3CN
Elizabeta Amir, Shlomo Rozen
DOI: 10.1039/B602594C
Assembled bright green fluorescent zinc coordination polymer
Ruibiao Fu, Shengchang Xiang, Shengmin Hu, Longsheng Wang, Yaming Li, Xihe Huang, Xintao Wu
DOI: 10.1039/B509695B
Insulated conducting polymers: manipulating charge transport using supramolecular complexes
Phoebe H. Kwan, Timothy M. Swager
DOI: 10.1039/B508399K
Enantioselective conjugate addition of phenylboronic acid to enones catalysed by a chiral tropos/atropos rhodium complex at the coalescence temperature
Chiara Monti, Cesare Gennari, Umberto Piarulli
DOI: 10.1039/B508832A
Metal complexes of selenophosphinates from reactions with (R2PSe)2Se: [M(R2PSe2)n] (M = ZnII, CdII, PbII, InIII, GaIII, CuI, BiIII, NiII; R = iPr, Ph) and [MoV2O2Se2(Se2PiPr2)2]
Chinh Q. Nguyen, Adekunle Adeogun, Mohammad Afzaal, Mohammad A. Malik, Paul O'Brien
DOI: 10.1039/B603198F
Regiochemical control of the catalytic asymmetric hydroboration of 1,2-diarylalkenes
Antonia Black, John M. Brown, Christophe Pichon
DOI: 10.1039/B508292G
Carbohydrate triazoles and isoxazoles as inhibitors of galectins-1 and -3
Denis Giguère, Ramesh Patnam, Marc-André Bellefleur, Christian St-Pierre, Sachiko Sato, René Roy
DOI: 10.1039/B517529A
Ferrimagnetic Mn2SnO4nanowires
Chan Woong Na, Doo Suk Han, Jeunghee Park, Younghun Jo, Myung-Hwa Jung
DOI: 10.1039/B601404F
You might also like
What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?
1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...
How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?
Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...
What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?
Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...
Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?
Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...
How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?
Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...
What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?
6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...
What is the market or research trend for 3-(3,4-dimethoxyphenyl)-2,5-dimethyl-N-(2-morpholin-4-ylethyl)pyrazolo[1,5-a]pyrimidin-7-amine (CAS: 900874-91-1)?
Research trends for this compound indicate a focus on its potential applications...
How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?
9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...
How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?
1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...
How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?
Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














