268 nm photodissociation of ClN3: a femtosecond velocity-map imaging study

Literature Information

Publication Date 2013-10-07
DOI 10.1039/C3CP53507J
Impact Factor 3.676
Authors

D. Staedter, E. Baynard, Peter C. Samartzis


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Abstract

We report the first time-resolved study of the photochemistry of chlorine azide (ClN3) by femtosecond velocity-map imaging (fs-VMI). The dissociation dynamics are initiated at 4.6 eV and the photofragments are detected by multiphoton ionization using an intense laser field centered at 803 nm. A dissociation time of 262 ± 38 fs was measured from the rising time of the co-fragments N3 and Cl. The time dependency of the angular distribution of N3, which converges from β2 ∼ 2 to β2 = 1.61 ± 0.07 in 170 ± 45 fs, reveals the parallel nature of the transition dipole moment.

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DOI: 10.1039/C6CP90005D

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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