Facile synthesis of novel poly(α-aminonitrile) networks through one-pot Strecker reactions
Literature Information
Publication Date
2012-02-08
DOI
10.1039/C2PY00002D
Impact Factor
5.582
Authors
Jiacheng Wang, Yoichi Masui, Makoto Onaka
View Original
Abstract
Organic polymeric networks (OPNWs) containing the repeated structural units of α-aminonitriles were successfully prepared for the first time in high yields (88–93%) via one-pot Strecker reactions of dialdehydes, di/tri-amines, and trimethylsilyl cyanide under catalyst-free conditions. The OPNWs possessing two functional groups (cyano- and secondary amino-groups) were very stable and insoluble in water and many common organic solvents, and also had high thermal stabilities.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
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