Multifunctional phosphonic acid self-assembled monolayers on metal oxides as dielectrics, interface modification layers and semiconductors for low-voltage high-performance organic field-effect transistors
Literature Information
Hong Ma, Orb Acton, Daniel O. Hutchins, Nathan Cernetic
Insulating and semiconducting molecular phosphonic acid (PA) self-assembled monolayers (SAMs) have been developed for applications in organic field-effect transistors (OFETs) for low-power, low-cost flexible electronics. Multifunctional SAMs on ultrathin metal oxides, such as hafnium oxide and aluminum oxide, are shown to enable (1) low-voltage (sub 2 V) OFETs through dielectric and interface engineering on rigid and plastic substrates, (2) simultaneous one-component modification of source–drain and dielectric surfaces in bottom-contact OFETs, and (3) SAM-FETs based on molecular monolayer semiconductors. The combination of excellent dielectric and interfacial properties results in high-performance OFETs with low-subthreshold slopes down to 75 mV dec−1, high Ion/Ioff ratios of 105–107, contact resistance down to 700 Ω cm, charge carrier mobilities of 0.1–4.6 cm2 V−1 s−1, and general applicability to solution-processed and vacuum-deposited n-type and p-type organic and polymer semiconductors.
Related Literature
Complexation dynamics of CH3SCN and Li+ in acetonitrile studied by two-dimensional infrared spectroscopy
YoungAh Kwon
DOI: 10.1039/C5CP02833G
Unified reaction pathways for the prebiotic formation of RNA and DNA nucleobases
Yassin Aweis Jeilani, Phoenix N. Williams, Sofia Walton, Minh Tho Nguyen
DOI: 10.1039/C6CP02686A
Electronic properties of epitaxial cerium oxide films during controlled reduction and oxidation studied by resonant inelastic X-ray scattering
Lucia Amidani, Pieter Glatzel, Paola Luches
DOI: 10.1039/C6CP04407G
Ion segregation in an ionic liquid confined within chitosan based chemical ionogels
A. Guyomard-Lack, N. Buchtová, B. Humbert, J. Le Bideau
DOI: 10.1039/C5CP04198H
Inverse internal conversion in C4− below the electron detachment threshold
Naoko Kono, Takeshi Furukawa, Hajime Tanuma, Jun Matsumoto, Haruo Shiromaru, Toshiyuki Azuma, Kaveh Najafian, Maria Susanne Pettersson, Bertil Dynefors, Klavs Hansen
DOI: 10.1039/C5CP02549D
Modulation of the aggregation properties of sodium deoxycholate in presence of hydrophilic imidazolium based ionic liquid: water dynamics study to probe the structural alteration of the aggregates
Niloy Kundu, Debasis Banik, Arpita Roy, Jagannath Kuchlyan, Nilmoni Sarkar
DOI: 10.1039/C5CP03906A
A rational synthesis of hierarchically porous, N-doped carbon from Mg-based MOFs: understanding the link between nitrogen content and oxygen reduction electrocatalysis
David Eisenberg, Wowa Stroek, Norbert J. Geels, Stefania Tanase, Marilena Ferbinteanu, Simon J. Teat, Pierre Mettraux, Ning Yan, Gadi Rothenberg
DOI: 10.1039/C6CP04132A
Concave or convex π-dimers: the role of the pancake bond in substituted phenalenyl radical dimers
Zhong-hua Cui, Abhinav Gupta, Miklos Kertesz
DOI: 10.1039/C5CP03759J
Alkali metal ion induced cube shaped mesoporous hematite particles for improved magnetic properties and efficient degradation of water pollutants
Mouni Roy, Milan Kanti Naskar
DOI: 10.1039/C6CP02442D
The efficiency of driving chemical reactions by a physical non-equilibrium is kinetically controlled
Tobias Göppel, Vladimir V. Palyulin, Ulrich Gerland
DOI: 10.1039/C6CP01034B
You might also like
What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?
When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...
What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?
4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...
How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?
5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...
What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?
The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...
Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?
[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...
What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?
3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...
What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?
N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...
What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?
This compound is primarily used in the pharmaceutical industry for the synthesis...
How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?
2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...
What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?
Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












![[3-(2,6-Dichlorophenyl)-5-isopropyl-1,2-oxazol-4-yl]methanol structure [3-(2,6-Dichlorophenyl)-5-isopropyl-1,2-oxazol-4-yl]methanol structure](https://static.chemtradehub.com/structs/278/278597-30-1-5c79.webp)
![Imidazo[1,2-c]pyrimidine structure Imidazo[1,2-c]pyrimidine structure](https://static.chemtradehub.com/structs/274/274-78-2-8b4c.webp)
