Hydrogen bonding of water in 3-methylpyridine studied by O 1s X-ray emission and absorption spectroscopy
Literature Information
Koichiro Sadakane, Takashi Tokushima, Yasunori Senba, Haruhiko Ohashi
O 1s X-ray emission and X-ray absorption spectroscopy is applied to probe hydrogen bonding of water (D2O) in 3-methylpyridine. Owing to element selectivity of X-ray spectroscopies the electronic structure of water in the binary mixture was observed selectively. Based on the observed spectral changes associated with hydrogen bonding in O 1s X-ray emission and X-ray absorption spectra, we have investigated the hydrogen bond of the mixture sample over a wide range of D2O concentrations (XD2O = 0.02–1.0) at room temperature under atmospheric pressure.
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