Controlled synthesis of radiolabelled amine methacrylate water-soluble polymers with end-groups of varying hydrophobicity and studies of adsorption behaviour
Literature Information
Publication Date
2011-11-04
DOI
10.1039/C1PY00397F
Impact Factor
5.582
Authors
Mark Long, David W. Thornthwaite, Suzanne H. Rogers, Francis R. Livens, Steve P. Rannard
View Original
Abstract
The effect of chain end chemistry on the behaviour of poly(2-(diethylamino)ethyl methacrylate) has been studied through the placement of various radioactive groups with increasing hydrophobicity at the chain end of the polymer. Controlled radical polymerisation with 14C-labelled initiators was used to form polymers of very similar chain length including doubly-labelled, fluorescent-radio polymers. Monitoring and quantification of behaviour was conducted purely using radiotechniques, without the need for fluorescence measurement, showing a clear impact on solid surface adsorption across a range of surface types (filter paper, photographic paper and hair). The studies presented here have clear implications for the study of polymer behaviour through low level fluorescent modification of water-soluble polymers.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
1-(4-Methylphenoxy)-3-(propan-2-ylamino)propan-2-ol
CAS Number:
5790-46-5
Molecular Formula:
C13H21NO2
![2-Methyl-2-propanyl [1-(3-nitro-2-pyridinyl)-4-piperidinyl]carbamate structure](https://static.chemtradehub.com/structs/833/833452-36-1-7af5.webp "2-Methyl-2-propanyl [1-(3-nitro-2-pyridinyl)-4-piperidinyl]carbamate structure")
2-Methyl-2-propanyl [1-(3-nitro-2-pyridinyl)-4-piperidinyl]carbamate
CAS Number:
833452-36-1
Molecular Formula:
C15H22N4O4
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