Recent advances in sunlight induced polymerization: role of new photoinitiating systems based on the silyl radical chemistry
Literature Information
Publication Date
2011-03-24
DOI
10.1039/C1PY00073J
Impact Factor
5.582
Authors
Jacques Lalevée, Jean Pierre Fouassier
View Original
Abstract
In the present paper, the recent development of new silyl chemistry based photoinitiating systems for sunlight induced polymerization is presented. The inherent issues of the effects of a low light intensity and oxygen inhibition are discussed. Some selected examples leading to tack free coatings in free radical photopolymerization (FRP) and cationic photopolymerization (CP) are provided. The use of the silyl radical chemistry to overcome the O2 inhibition is presented. The sunlight induced polymerization might be a promising way for practical low cost and environmentally friendly curing processes. The use of renewable epoxy monomers (such as epoxidized soybean oil (ESO), epoxidized linseed oil (ELO) or limonene dioxide (LDO)) in combination with a sunlight induced process also appears particularly worthwhile for green chemistry applications.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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2-Methyl-2-propanyl [(2S)-1-hydroxy-3-(4-hydroxyphenyl)-2-propanyl]carbamate
CAS Number:
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Molecular Formula:
C14H21NO4
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CAS Number:
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Molecular Formula:
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