Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet‡

Literature Information

Publication Date 2011-09-01
DOI 10.1039/C1CC14186D
Impact Factor 6.222
Authors

Robin J. Blagg, Floriana Tuna, Eric J. L. McInnes, Richard E. P. Winpenny


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Abstract

Pentametallic Ln complexes of formula [Ln5O(OiPr)13] have been made, where LnIII = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.

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