Weak Ag⋯Ag and Ag⋯π interactions in templating regioselective single and double [2+2] reactions of N,N′-bis(3-(4-pyridyl)acryloyl)–hydrazine: synthesis of an unprecedented tricyclohexadecane ring system

Literature Information

Publication Date 2011-08-22
DOI 10.1039/C1CC13994K
Impact Factor 6.222
Authors

Ramkinkar Santra, Kaustuv Banerjee, Kumar Biradha


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Abstract

Synthesis of a stereospecific four–twelve–four fused tricyclic compound containing a tetraamide macrocycle has been achieved by the solid state [2+2] reaction through utilization of Ag⋯Ag interaction. The influence of anions on crystal packing has been utilized for the synthesis of a regioselective mono cyclobutane compound via the Ag⋯π interactions.

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