Synthesis, characterization and ethylene oligomerization behaviour of 8-(1-aryliminoethylidene)quinaldinylnickel dihalides

Literature Information

Publication Date 2011-02-08
DOI 10.1039/C0CY00002G
Impact Factor 6.119
Authors

Shengju Song, Tianpengfei Xiao, Tongling Liang, Fosong Wang, Carl Redshaw, Wen-Hua Sun


View Original

Abstract

A series of 8-(1-aryliminoethylidene)quinaldines and the nickel halides thereof were synthesized and characterized, and the molecular structures of two representative nickel complexes were confirmed by single-crystal X-ray diffraction studies. Upon treatment with diethylaluminium chloride (Et2AlCl), the nickel pro-catalysts exhibited high activity for ethylene oligomerization (1.24–1.83 × 106 g mol−1(Ni) h−1) with good thermal stability at 60 °C under 10 atm of ethylene. The influence of the reaction parameters on the catalytic behaviour was investigated for these nickel-based systems, including variation of Al/Ni molar ratio and reaction temperature. Furthermore, the effect of the ancillary ligand Ph3P was also probed.

Related Literature

NMR and ion selective electrode studies of hydraphile channels correlate with biological activity in E. coli and B. subtilis

W. Matthew Leevy, Michelle E. Weber, Paul H. Schlesinger

2004-11-25 Communication

DOI: 10.1039/B413588A

Phosphinine stabilised gold nanoparticles; synthesis and immobilisation on mesoporous materials

Audrey Moores, Frédéric Goettmann, Clément Sanchez, Pascal Le Floch

2004-10-27 Communication

DOI: 10.1039/B412553C

A novel catalyst with high activity for polyhydric alcohol oxidation: nanosilver/zeolite film

Jiang Shen, Wei Shan, Yahong Zhang, Junming Du, Hualong Xu, Kangnian Fan, Wei Shen, Yi Tang

2004-11-15 Communication

DOI: 10.1039/B412986E

Synthesis of meso-β doubly linked porphyrin tapes

Akihiko Tsuda, Yasuyuki Nakamura, Atsuhiro Osuka

2003-04-07 Communication

DOI: 10.1039/B302032K

Ensemble hybridisation – a new method for exploring sequence dependent fluorescence of dye–nucleic acid conjugates

Olaf Köhler, Dilip Venkatrao Jarikote, Oliver Seitz

2004-10-14 Communication

DOI: 10.1039/B411877D

Influence of substrate on self-assembled photonic crystal

Sachiko I. Matsushita

2004-02-09 Communication

DOI: 10.1039/B313410E

Reduction of nitroaromatics to arylnitrenium ions by vinyl halide cations

Hao Chen, Xubin Zheng, Pengxiang Yang, R. Graham Cooks

2004-02-12 Communication

DOI: 10.1039/B314713D

Total synthesis of (+)-belactosin A

Alan Armstrong, James N. Scutt

2004-01-27 Communication

DOI: 10.1039/B316142K

Trimethyltriazacyclohexane as bridging ligand for triangular Cu3 units and C–H hydride abstraction into a Cu6 cluster

Randolf D. Köhn, Zhida Pan, Mary F. Mahon, Gabriele Kociok-Köhn

2003-05-02 Communication

DOI: 10.1039/B302670A

Poly(9,9′-spirobifluorene-manganese porphyrin): a new catalytic material for oxidation of alkenes by iodobenzene diacetate and iodosylbenzene

Cyril Poriel, Yann Ferrand, Paul le Maux, Joëlle Raul-Berthelot, Gerard Simonneaux

2003-04-02 Communication

DOI: 10.1039/B301717F

You might also like

Compound Q&A

What industries use (1R,3S)-1,3-Cyclopentanediol (CAS: 16326-97-9)?

(1R,3S)-1,3-Cyclopentanediol finds applications in various industries. In the ph...

16326-97-9(1R,3S)-1,3-Cyclopen...
Compound Q&A

What precautions should be taken when handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine (CAS: 637-31-0)?

When handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine, it i...

637-31-0N'-[4-(Dimethylamino...
Compound Q&A

Are there alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine (CAS: 1352318-16-1) in synthesis?

There are several alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine in ...

1352318-16-15-(2,4-Difluoropheny...
Compound Q&A

What regulatory guidelines apply to 1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6)?

1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6) must comply with the Globally...

382141-68-61-(3-Methoxyphenoxy)...
Compound Q&A

Is Tetrodotoxin Citrate (CAS: 18660-81-6) safe?

Tetrodotoxin Citrate is extremely dangerous and should be handled with extreme c...

18660-81-6Tetrodotoxin Citrate
Compound Q&A

What are the main uses of 2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9)?

2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9) i...

225641-84-92-Methyl-2-propanyl ...
Compound Q&A

How should waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) be handled?

Waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) ...

16261-80-64-(2-Hydroxyhexafluo...
Compound Q&A

How is 2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl}carbamate (CAS: 102507-19-7) typically synthesized?

2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl...

102507-19-72-Methyl-2-propanyl ...
Compound Q&A

What is Benzeneethanamine, α-ethyl-, hydrochloride (1:1) (CAS: 20735-15-3)?

Benzeneethanamine, α-ethyl-, hydrochloride (1:1) is an organic compound with the...

20735-15-3Benzeneethanamine, α...
Compound Q&A

Are there alternatives to 3-{(E)-[4-(Dimethylamino)phenyl]diazenyl}benzoic acid (CAS: 20691-84-3) in synthesis?

In the synthesis of compounds similar to 3-{(E)-[4-(Dimethylamino)phenyl]diazeny...

20691-84-33-{(E)-[4-(Dimethyla...

Source Journal

Catalysis Science & Technology

Catalysis Science & Technology
CiteScore: 5.91
Self-citation Rate: 4.5%
Articles per Year: 600

Catalysis Science & Technology is committed to publishing research reporting high-quality, cutting-edge developments across the catalysis community at large. The journal places equal focus on publications from the heterogeneous, homogeneous, thermo-, electro-, photo-, organo- and biocatalysis communities. Works published in the journal feature a balanced mix of fundamental, technology-oriented, experimental, computational, digital and data-driven original research, thus appealing to catalysis practitioners in both academic and industrial environments. Original research articles published in the journal must demonstrate new catalytic discoveries and/or methodological advances that represent a significant advance on previously published work, from the molecular to the process scales. We welcome rigorous research in a wide range of timely or emerging applications related to the environment, health, energy and materials. Catalysis Science & Technology publishes Communications, Articles, Reviews and Perspectives. More details regarding manuscript types may be found in the Information for Authors section.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.