A variable series resistance mechanism to explain the negative capacitance observed in impedance spectroscopy measurements of nanostructured solar cells
Literature Information
Juan Bisquert
A simple model for conductivity modulation in a recombination diode is discussed to explain the observation of negative capacitance at forward bias observed in many optoelectronic devices. We formulate the basic recombination-modulation model in terms of an equivalent circuit for small ac perturbation and discuss the application of the results in measurements of impedance spectroscopy of dye-sensitized solar cells, organic solar cells and related systems.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











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