Diblock copolymer membranes investigated by single-particle tracking
Literature Information
Chandrashekara R. Haramagatti, Felix H. Schacher, Axel H. E. Müller, Jürgen Köhler
We report a study on particle diffusion in membranes formed from polystyrene-block-poly(2-(dimethylamino)ethyl methacrylate) (PS-b-PDMAEMA) diblock copolymers. The membranes were investigated by scanning electron microscopy and by single-particle tracking employing carboxy-functionalized polystyrene beads loaded with a fluorophore as spectroscopic probes. From the diffusion trajectories we extracted the domain size distribution of the membranes and the local diffusion coefficient of the beads as a function of the size of the beads. The single-particle tracking data revealed that the effective domain sizes of the membranes are reduced with respect to the domain sizes obtained from scanning electron microscopy, reflecting the confined diffusion of the probe particles due to interactions with the domain walls. This is corroborated by a clear correlation between the diffusion coefficient of an individual polystyrene bead and the size of the actual domain to which it is confined.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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