Probing interfacial solvation of incipient self-assembled monolayers

Literature Information

Publication Date 2010-09-20
DOI 10.1039/C0CP01423K
Impact Factor 3.676
Authors

Juan José Calvente, Rafael Andreu


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Abstract

Poor solvation of alkylthiols in a water-rich interfacial environment is shown to induce a dispersion of energetically-distinct states above a critical value of the hydrocarbon chain length, which depends on the hydrophilicity of the terminal group. Switching between single and dispersed states can be achieved by an adequate choice of the solvent composition.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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