Solid-state photoelectron transfer in powdery nanocomposites comprised of a sensitiser, photoacid generators and silicananoparticles

Literature Information

Publication Date 2011-02-21
DOI 10.1039/C0CP00034E
Impact Factor 3.676
Authors

Shinji Horie, Shusaku Nagano


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Abstract

The dry beads milling of a mixture of 9,10-dipropoxyanthracene (DPA) as an electron donor and surface-modified silica nanoparticles was conducted in the absence or in the presence of a photoacid generator (PAG) as an electron acceptor to give powdery nanocomposites. Fluorescence measurements indicated no mechanochemical change in the crystal structure of DPA after the nanohybridisation. The co-milling with PAG resulted in solid-state fluorescence quenching, whereas quenching efficiency was considerably dependent on the nature of PAG. The solid-state sensitised photoacid generation through the electron transfer was demonstrated by the solid-state photocolouration of leuco-dye of crystal violet lactone.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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