Infrared spectroscopy and vibrational exciton modeling of crystalline, polycrystalline and amorphous acetylene aerosol particles

Literature Information

Publication Date 2010-06-03
DOI 10.1039/C002525A
Impact Factor 3.676
Authors

Thomas C. Preston, George Firanescu, Ruth Signorell


View Original

Abstract

Mid-infrared spectra of acetylene aerosol particles generated under conditions relevant to Titan's atmosphere are analyzed in terms of the vibrational exciton model. The analysis reveals that acetylene aerosol particles do not form single crystals below 110 K as previously assumed. Instead, less ordered structures such as polycrystalline particles with orthorhombic crystalline domains or possibly partially amorphous particles derived from an orthorhombic crystal structure are found to be very stable. Annealing of these particles leads to the formation of crystalline particles with an orthorhombic crystal structure. Particles with a cubic crystal structure were never observed at these temperatures in agreement with the phase behavior of bulk acetylene.

Related Literature

Front cover

2023-11-15 Cover

DOI: 10.1039/D3NP90049E

Efficient and durable vanadium flow batteries enabled by high-performance fluorinated poly(aryl piperidinium) membranes

Tao Ban, Maolian Guo, Yajie Wang, Jiawang Ma, Xinxin Wang, Zihui Wang, Xiuling Zhu

2023-10-17 Paper

DOI: 10.1039/D3TA05382B

Facile one-pot synthesis of a waste copper phthalocyanine-derived nanocomposite for efficiently removing dyes from wastewater

Munazza Munshi, Tanzila Khan, Madhuri Bhakare, Ankita Kadam, Surajit Some

2024-01-09 Paper

DOI: 10.1039/D3NJ05351B

Enhancing photocatalytic CO2 reduction to formate through one-pot self-assembly of a semiartificial cell

Yixin Hong, Jianyu Han, Zhi Wang, Xiaofei Gu, Tianyi Huang, Yafeng Wu, Songqin Liu

2023-10-24 Paper

DOI: 10.1039/D3TA04556K

Construction of a metal–oxide interface through alloy nanoparticles to enhance CO2 electrolysis

Xu Huang, Hui Sun, Xuewei He, Yunkai Ruan, Lizhen Gan

2023-12-13 Paper

DOI: 10.1039/D3NJ04854C

Electrochemical aminotrifluoromethylation of unactivated alkenes with Langlois’ reagent as the CF3 source

Tongshun An, Xiaowen Qin, Chenwei Liu, Weiheng Yuan, Tanyu Song, Zhiping Yin

2023-12-26 Paper

DOI: 10.1039/D3NJ04705A

Crystal structure, magnetic properties and theoretical study of a bithiazolebis(oxamate)-containing [Ni II3] helicate

Lucas H. G. Kalinke, Mariany S. Silva, Ana K. Valdo, Felipe T. Martins, Nicolás Moliner, Miguel Julve, Francesc Lloret, Joan Cano, Danielle Cangussu

2024-01-08 Paper

DOI: 10.1039/D3NJ04701F

Natural ten-membered lactones: sources, structural diversity, biological activity, and intriguing future

Vsevolod Dubovik, Anna Dalinova, Alexander Berestetskiy

2023-10-27 Review Article

DOI: 10.1039/D3NP00013C

Microporous organic nanoparticles bearing tri-Zn macrocycles: heterogeneous catalysts for the conversion of biomass-derived furan esters to polymer platforms

June Young Jang, Gang Min Lee, Jong Doo Lee, Seung Uk Son

2023-10-20 Communication

DOI: 10.1039/D3TA04797K

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.