New organic–inorganic hybrid microporous organosilica having high metal ion adsorption capacity
Literature Information
Manidipa Paul, Nabanita Pal, P. R. Rajamohanan, Bharat S. Rana, Anil K. Sinha, Asim Bhaumik
A new microporous organic–inorganic hybrid organosilica LHMM-2 containing a bis(propyliminomethyl)benzene moiety inside the framework has been synthesized hydrothermally without using any template or structure-directing agent. Powder XRD and TEM image analyses suggest a new disordered microporous structure with pores of dimension ca. 0.54 nm, and 13C and 29Si MAS NMR and spectroscopic results indicate the presence of bridging organic bis(propyliminomethyl)benzene moiety in this framework. TPD-NH3 results suggested that nearly 5 times as much bis(propyliminomethyl)benzene moiety is located inside the micropore walls (matrix) than in the surface of the pores. LHMM-2 shows very high adsorption capacity for metal cations like Fe3+, Cu2+ and Zn2+.
Recommended Journals
Related Literature
Different effects of water molecules on CO oxidation with different reaction mechanisms
Shan Ping Liu, Ming Zhao, Guo En Sun, Wang Gao, Qing Jiang
DOI: 10.1039/C8CP00035B
Improved fill factor in inverted planar perovskite solar cells with zirconium acetate as the hole-and-ion-blocking layer
Xuewen Zhang, Chunjun Liang, Mengjie Sun, Huimin Zhang, Chao Ji, Zebang Guo, Yajun Xu, Fulin Sun, Qi Song, Zhiqun He
DOI: 10.1039/C8CP00563J
The kinetics and mechanism of oxidation of reduced phosphovanadomolybdates by molecular oxygen: theory and experiment in concert ‡
Alexander M. Khenkin, Irena Efremenko, Jan M. L. Martin, Ronny Neumann
DOI: 10.1039/C7CP08610E
Visible-light-driven CO2 photoreduction over ZnxCd1−xS solid solution coupling with tetra(4-carboxyphenyl)porphyrin iron(iii) chloride
Xuehua Zhang, Chunchao Hou, Lin Lin
DOI: 10.1039/C8CP02774A
Optical spectroscopy of isolated flavins: photodissociation of protonated lumichrome
Alexander Sheldrick, David Müller, Alan Günther, Pablo Nieto, Otto Dopfer
DOI: 10.1039/C8CP00590G
B3@Si12+: strong stabilizing effects of a triatomic cyclic boron unit on tubular silicon clusters
Hung Tan Pham, Thi Tuyet Mai Dang, Long Van Duong
DOI: 10.1039/C8CP00380G
Multi-channel dynamics in high harmonic generation of aligned CO2: ab initio analysis with time-dependent B-spline algebraic diagrammatic construction
M. Ruberti, P. Decleva, V. Averbukh
DOI: 10.1039/C7CP07849H
Insights into the interfacial strengthening mechanisms of calcium-silicate-hydrate/polymer nanocomposites
Dongshuai Hou, Pan Feng, Jiao Yu, Jinyang Jiang
DOI: 10.1039/C8CP00328A
Half-metallic and magnetic semiconducting behaviors of metal-doped blue phosphorus nanoribbons from first-principles calculations
Shun-Jin Peng, Kai-Ming Wu, Kai-Lun Yao, Chee-Leung Mak, Chi-Hang Lam
DOI: 10.1039/C7CP08635K
Uncovering reaction sequences on surfaces through graphical methods
Mina Jafari, Paul M. Zimmerman
DOI: 10.1039/C8CP00044A
You might also like
How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?
Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...
How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?
N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...
What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?
The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...
How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?
Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...
What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?
2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...
What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?
1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...
Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?
Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...
What precautions should be taken when handling 1-((2R,3R,4R,5R)-5-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-4-hydroxy-3-methoxytetrahydrofuran-2-yl)-5-methylpyrimidine-2,4(1H,3H)-dione (CAS: 153631-19-7)?
Proper personal protective equipment (PPE) must be worn when handling this compo...
What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?
When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...
Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?
Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












![2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate structure 2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate structure](https://static.chemtradehub.com/structs/127/1279090-25-3-1b84.webp)
