Lability of metal complexes at spherical sensors. Dynamic voltammetric measurements
Literature Information
Ángela Molina, Francisco Martínez-Ortiz, Eduardo Laborda, Jaume Puy
The diffusive-kinetic steady-state (dkss) approximation is applied to the case of a metal ion reaching a transforming/consuming spherical surface (sensor) when the ion is involved in a complexation reaction in solution. Simple time-dependent expressions for the surface metal flux, the lability degree and the half-wave potential are presented, valid for any value of the ratio of concentrations at the surface and the sensor radius. The solution presented is compared with other theoretical approaches, such as the kinetic steady state (kss) and the total steady state (tss), pointing out that the easy dkss approach is much more accurate than the tss one to study the metal flux and the lability degree for any value of the radius, from ultramicro to planar sensors.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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