Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts‡

Literature Information

Publication Date 2009-09-16
DOI 10.1039/B915759J
Impact Factor 6.222
Authors

Takushi Shiomi, Takahiro Adachi, Kenji Toribatake, Li Zhou, Hisao Nishiyama


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Abstract

Chiral rhodium–bisoxazolinylphenyl acetate complexes exhibited high catalytic activity for the β-boration of α,β-unsaturated carbonyl compounds with bis(pinacolato)diboron in the presence of sodium t-butoxide with enantioselectivity up to 97%.

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Back cover

Front/Back Matter

DOI: 10.1039/C1OB90047A

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