New enantiopure NHCs derived from camphor

Literature Information

Publication Date 2009-08-18
DOI 10.1039/B911476A
Impact Factor 6.222
Authors

Peddiahgari Vasu Govardhana Reddy, Sobia Tabassum, Amélie Blanrue, René Wilhelm


View Original

Abstract

A new class of enantiopure carbene precursors based on cheap camphor has been developed, and a restricted rotation of one N-substituent due to the C-10 methyl group of the camphor skeleton has been found; in situ prepared corresponding carbenes revealed the same behaviour.

Related Literature

Cationic peptidopolysaccharides synthesized by ‘click’ chemistry with enhanced broad-spectrum antimicrobial activities

Yajuan Su, Liang Tian, Meng Yu, Qiang Gao, Dehui Wang, Yuewei Xi, Peng Yang, Bo Lei, Peng Li

2017-05-08 Paper

DOI: 10.1039/C7PY00528H

Traceless switch organocatalysis enables multiblock ring-opening copolymerizations of lactones, carbonates, and lactides: by a one plus one approach in one pot

Xin Wang, Jiaqi Liu, Songquan Xu, Jiaxi Xu, Xianfu Pan, Jingjing Liu, Saide Cui, Zhenjiang Li, Kai Guo

2016-08-22 Paper

DOI: 10.1039/C6PY01107A

Chemoselective synthesis of macrocyclic poly(methylvinylsiloxane)s via metathetical ring-expanding polymerization of oligomeric cyclosiloxanes by sequential (MeVinylSi-O-) insertion reactions

Ze Li, Chunyong Wu, Lifeng Liu, Meijiang Li, Xiongfa Yang, Chaowei Hao, Qiu Chen, Ziqiang Hu, Mengxian Luo, Guoqiao Lai, Tien-Yau Luh

2017-01-30 Paper

DOI: 10.1039/C6PY01841F

Post-polymerization modification of the side chain in optically active polymers by thiol–ene reaction

Naoya Kanbayashi, Sou Miyamoto, Yuki Ishido, Taka-aki Okamura, Kiyotaka Onitsuka

2016-12-06 Paper

DOI: 10.1039/C6PY01946C

A cellulose-based chiral fluorescent sensor for aromatic nitro compounds with central, axial and planar chirality

Tomoyuki Ikai, Daisuke Suzuki, Ken-ichi Shinohara, Katsuhiro Maeda, Shigeyoshi Kanoh

2017-03-20 Paper

DOI: 10.1039/C7PY00285H

Trithiocarbonates as intrinsic photoredox catalysts and RAFT agents for oxygen tolerant controlled radical polymerization

Q. Fu, K. Xie, T. G. McKenzie, G. G. Qiao

2017-01-26 Paper

DOI: 10.1039/C6PY01994C

The para-fluoro-thiol reaction as a powerful tool for precision network synthesis

Federica Cavalli, Sven O. Steinmueller

2017-06-06 Communication

DOI: 10.1039/C7PY00812K

Inside front cover

Cover

DOI: 10.1039/C7PY90085F

You might also like

Compound Q&A

What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?

When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...

16712-20-2Lithium chloride hyd...
Compound Q&A

Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?

4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...

690261-92-84-(4H-1,2,4-Triazol-...
Compound Q&A

How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?

Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...

16733-85-01,3-Thiazole-2-carbo...
Compound Q&A

What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?

5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...

934175-58-35-(Difluoromethyl)-2...
Compound Q&A

How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?

Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...

22288-79-5Methyl 3-acetamido-2...
Compound Q&A

What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?

4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...

34846-65-64-Isoquinolinecarbon...
Compound Q&A

How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?

Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...

877309-59-6Methyl 1H-1,2,3-tria...
Compound Q&A

What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?

6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...

1160791-13-86-Bromo[1,3]thiazolo...
Compound Q&A

Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?

(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...

23651-95-8(2S,3S)-2-Ammonio-3-...
Compound Q&A

What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?

7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....

1293987-84-47-bromo-3-methyl-3,4...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.