![1-[4-(4-Methyl-1H-imidazol-1-yl)phenyl]ethanone structure](https://static.chemtradehub.com/structs/142/142161-53-3-7f55.webp "1-[4-(4-Methyl-1H-imidazol-1-yl)phenyl]ethanone structure")
Direct optical observations of vesicular self-assembly in large-scale polymeric structures during photocontrolled biphasic polymerization
Literature Information
Publication Date
2016-11-14
DOI
10.1039/C6PY01497F
Impact Factor
5.582
Authors
Jan K. Szymański
View Original
Abstract
In this report, we employ a photo-controlled polymerization protocol featuring a fluorescent initiator to follow the evolution of the generated self-assembled microscopic structures in a phase-separating dispersion polymerization medium. We observe the growth of polymer vesicles with final diameters of tens of microns. The formed structures respond to illumination with visible light at the absorbance maximum of the photoinitiator, demonstrating that the reaction mixture remains active even after transferring to an optical microscope slide and that the “blebbing” of vesicles and their growth continue until a mature size is reached.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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8-Bromo-6-fluoro[1,2,4]triazolo[1,5-a]pyridin-2-amine
CAS Number:
1257705-51-3
Molecular Formula:
C6H4BrFN4
Ethyl 2,4-bis(trifluoromethyl)-5-pyrimidinecarboxylate
CAS Number:
188781-15-9
Molecular Formula:
C9H6F6N2O2
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