The trinity of polyoxometalates: connecting {M12} Keggin and {M18} Dawson clusters to triangles

Literature Information

Publication Date 2009-04-16
DOI 10.1039/B903206A
Impact Factor 6.222
Authors

Scott G. Mitchell, Sumit Khanra, Haralampos N. Miras, Thomas Boyd, De-Liang Long, Leroy Cronin


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Abstract

Two topologically equivalent triangular POM aggregates based upon the Keggin (1) and Dawson (2) cluster species, with distinctive double {W–O–M} intra-molecular linkages involving MnIII and CoIII ions are presented; both these compounds demonstrate electrocatalytic activity.

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