Room-temperature aerobic formation of a stable aryl–Cu(iii) complex and its reactions with nucleophiles: highly efficient and diverse arene C–H functionalizations of azacalix[1]arene[3]pyridine

Literature Information

Publication Date 2009-04-06
DOI 10.1039/B902946J
Impact Factor 6.222
Authors

Bo Yao, De-Xian Wang, Zhi-Tang Huang, Mei-Xiang Wang


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Abstract

Under very mild aerobic conditions, azacalix[1]arene[3]pyridine underwent highly efficient C–H activation with Cu(ClO4)2·6H2O to form a stable aryl–Cu(III) complex which reacted rapidly with various nucleophiles at ambient temperature to afford diverse functionalized azacalix[1]arene[3]pyridine derivatives in excellent yields.

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