An intensely and oxygen independent phosphorescent gold(i)–silver(i) complex: “trapping” an Au8Ag10 oligomer by two gold-alkynyl-diphosphine molecules

Literature Information

Publication Date 2009-03-30
DOI 10.1039/B901893J
Impact Factor 6.222
Authors

Igor O. Koshevoy, Yi-Chih Lin, Antti J. Karttunen, Matti Haukka, Pi-Tai Chou, Sergey P. Tunik, Tapani A. Pakkanen


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Abstract

The molecular heterometallic [{Au8Ag10(C2Ph)16}{(PhC2Au)2PPh2(C6H4)3PPh2}2]2+ aggregate of unprecedented topology was obtained and structurally characterized; this compound demonstrates unusually effective phosphorescence, which displays negligible oxygen quenching due to shielding of emissive central cluster by the outer shell of the molecule.

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