Probing the hydrogen-bond network of watervia time-resolved soft X-ray spectroscopy

Literature Information

Publication Date 2009-03-10
DOI 10.1039/B822210J
Impact Factor 3.676
Authors

Nils Huse, Haidan Wen, Dennis Nordlund


View Original

Abstract

We report time-resolved studies of hydrogen bonding in liquid H2O, in response to direct excitation of the O–H stretch mode at 3 μm, probed via soft X-ray absorption spectroscopy at the oxygen K-edge. This approach employs a newly developed nanofluidic cell for transient soft X-ray spectroscopy in the liquid phase. Distinct changes in the near-edge spectral region (XANES) are observed, and are indicative of a transient temperature rise of 10 K following transient laser excitation and rapid thermalization of vibrational energy. The rapid heating occurs at constant volume and the associated increase in internal pressure, estimated to be 8 MPa, is manifested by distinct spectral changes that differ from those induced by temperature alone. We conclude that the near-edge spectral shape of the oxygen K-edge is a sensitive probe of internal pressure, opening new possibilities for testing the validity of water models and providing new insight into the nature of hydrogen bonding in water.

Related Literature

Rotational spectra of van der Waals complexes: pyrrole–Ne and pyrrole–Ne2

Isabel Peña, Carlos Cabezas

2020-10-26 Paper

DOI: 10.1039/D0CP04580B

Superconductivity in an organometallic compound

Liu-Cheng Chen, Hui Yang, Ming-An Fu, Jia Cheng, Xiao-Lin Wu, Yun Gao, Zhong-Bing Huang, Xiao-Jia Chen

2019-10-14 Paper

DOI: 10.1039/C9CP04227J

Atomistic origins of charge traps in CdSe nanoclusters

Natalia Bushlanova, Yurii Uspenskii

2020-10-30 Paper

DOI: 10.1039/D0CP05139J

Na2CO3-modified CaO-based CO2 sorbents: the effects of structure and morphology on CO2 uptake

Alexey Kurlov, Agnieszka M. Kierzkowska, Thomas Huthwelker, Paula M. Abdala, Christoph R. Müller

2020-10-15 Paper

DOI: 10.1039/D0CP04410E

The simultaneous recognition mechanism of cations and anions using macrocyclic–iodine structures: insights from dispersion-corrected DFT calculations

Renato Pereira Orenha, Glaucio Régis Nagurniak, Matheus Cachoeira Colaço, Giovanni Finoto Caramori, Maurício Jeomar Piotrowski, Krys Elly de Araújo Batista, Alvaro Muñoz-Castro, Breno de Almeida Silva, Benjamim José Esteves, Renato Luis Tame Parreira

2020-10-06 Paper

DOI: 10.1039/D0CP04291A

Luminescence and energy transfer mechanisms in photo-thermo-refractive glasses co-doped with silver molecular clusters and Eu3+

Dmitriy V. Marasanov, Leonid Yu. Mironov, Yevgeniy M. Sgibnev, Ilya E. Kolesnikov, Nikolay V. Nikonorov

2020-10-12 Paper

DOI: 10.1039/D0CP02786C

Micro-solvation of CO in water: infrared spectra and structural calculations for (D2O)2–CO and (D2O)3–CO

A. J. Barclay, A. Pietropolli Charmet, K. H. Michaelian, A. R. W. McKellar, N. Moazzen-Ahmadi

2019-11-21 Paper

DOI: 10.1039/C9CP05480D

New approach to increase the sensitivity of Tb–Eu-based luminescent thermometer

Alexander I. Dalinger, Leonid S. Lepnev, Sergey Z. Vatsadze

2020-10-07 Communication

DOI: 10.1039/D0CP04909C

Distance dependent energy transfer dynamics from a molecular donor to a zeolitic imidazolate framework acceptor

Wenhui Hu, Fan Yang, Nick Pietraszak, Jing Gu, Jier Huang

2020-10-20 Communication

DOI: 10.1039/D0CP03995K

You might also like

Compound Q&A

How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?

Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...

88634-80-42-Ethyl-4-Methyl-1H-...
Compound Q&A

What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?

Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...

1385031-14-0Triethoxy(octyl)sila...
Compound Q&A

Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?

Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...

864724-64-13-iodo-7-nitro-1H-in...
Compound Q&A

Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?

Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...

266317-71-9Benzene, bis[(trimet...
Compound Q&A

Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?

Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...

1452-17-1Isothiazole-3-carbon...
Compound Q&A

Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?

(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...

873-63-2(3-Chlorophenyl)meth...
Compound Q&A

How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?

(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...

959583-98-3(2S,3S)-2-Hydroxy-3-...
Compound Q&A

What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?

Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...

788081-99-2Methyl 2-(bromomethy...
Compound Q&A

What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?

6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...

904805-36-36,8-Dibromoimidazo[1...
Compound Q&A

Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?

3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...

573675-27-13-Amino-5-bromo-2-py...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.