Photoinduced multi-electron transfer in the Dn–A system consisting of multi-phthalocyanines linked to one carbon nanotube
Literature Information
Xiaofeng Cui, Qiang Liu, Fushi Zhang
A Dn–A model in which a carbon nanotube (nanoscaled electron acceptor A) is attached with a number of electron donors (Dn), i.e.amino phthalocyanines, was employed to reveal the different nature of photoinduced electron transfer (PeT) in the nanoscaled model from that of a usual one-to-one linked D–A system, which is known to form the single-charge separation state D˙+–A˙−via well-studied single-electron transfer. For the Dn–A system, however, a one-step multi-electron transfer from multi donors to the same acceptor occurs simultaneously to generate a long-lived multiple-charge separation state Dn˙+–A˙n− (n > 1), which is desirable for efficiently mimicking PSII in photosynthesis.
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